Identify the type of electromeric effect ($E$-effect) in the following reactions:
$(a) >C=C< + CN^{-} \to -C(CN)-C^{-}-$
$(b) >C=C< + H^{+} \to -C^{+}-CH-$

  • A
    $+E$ effect in both
  • B
    $-E$ effect in both
  • C
    $(a)$ is $-E$ effect and $(b)$ is $+E$ effect
  • D
    $(a)$ is $+E$ effect and $(b)$ is $-E$ effect

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Identify the most stable species in the following set of ions giving reasons.
$(a) \ \stackrel{+}{C} H_{3}, \stackrel{+}{C} H_{2} Br, \stackrel{+}{C} HBr_{2}, \stackrel{+}{C} Br_{3}$
$(b) \ \stackrel{\Theta}{C} H_{3}, \stackrel{\Theta}{C} H_{2} Cl, \stackrel{\Theta}{C} HCl_{2}, \stackrel{\Theta}{C} Cl_{3}$

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